Aureille is a good base for travellers who want the Alpilles without sleeping in the busiest villages.
From here, you can drive to Eygalières, Mouriès, Maussane-les-Alpilles, Les Baux-de-Provence and Saint-Rémy-de-Provence. Each gives a different version of the region: markets, stone houses, terraces, galleries, olive mills, limestone views and good village restaurants.
The Alpilles Regional Nature Park is close in every direction. Walks can start almost from the village, with trails through garrigue, olive groves, rocky slopes and viewpoints over the plain.
Les Baux and the Carrières des Lumières are the obvious classic outing. Saint-Rémy is the one for markets, shops, cafés and the Van Gogh / Saint-Paul-de-Mausole story. Eygalières and Maussane work well for quieter lunches and village wandering.
The wider region opens easily too: Arles, Avignon, the Camargue, Aix-en-Provence and the Luberon can all be reached for day trips, depending on how much driving you want.